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Yeah, the big sticking point here is that it's an absolute nightmare to try and figure out what is going on at the interfaces.

Yeah, the big sticking point here is that it's an absolute nightmare to try and figure out what is going on at the interfaces. Current theory does not do a very good job at all and is monstrously computationally expensive, especially if they are going to wave their hands and point to "wavefunction overlap". You need a 1-D electronic theory to describe singlet fission - talking about wavefunctions is meaningless when you're in a bosonic sector. You need to talk about _fields_, not a mention of which I see in these papers. EDIT: To be less cryptic, this is what I mean: https://en.wikipedia.org/wiki/Second_quantization

Posted by selimthegrim on Oct 9, 2014, 10:11 PM

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Yeah, the big sticking point here is that it's an absolute nightmare to try and figure out what is going on at the interfaces.

selimthegrimOct 9, 2014, 10:11 PM

Yeah, the big sticking point here is that it's an absolute nightmare to try and figure out what is going on at the interfaces. Current theory does not do a very good job at all and is monstrously computationally expensive, especially if they are going to wave their hands and point to "wavefunction overlap". You need a 1-D electronic theory to describe singlet fission - talking about wavefunctions is meaningless when you're in a bosonic sector. You need to talk about _fields_, not a mention of which I see in these papers. EDIT: To be less cryptic, this is what I mean: https://en.wikipedia.org/wiki/Second_quantization

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